Optimization Of Coffee Grounds and Fly Ash Based Adsorbent Composition with Phosphoric Acid Activator for Tofu Industry Liquid Waste Purification

Authors

  • Mustika Agustini Alfithroh Politeknik Negeri Bandung, Indonesia
  • Khalaida Fania Fattah Politeknik Negeri Bandung, Indonesia
  • Yusup Muhammad Zulfikar Politeknik Negeri Bandung, Indonesia
  • Zakiyyah Tsuroyyaa Politeknik Negeri Bandung, Indonesia
  • Feby Nurghaida Zaharani Politeknik Negeri Bandung, Indonesia
  • Alfiana Adhitasari Politeknik Negeri Bandung, Indonesia

DOI:

https://doi.org/10.33603/jgst.v9i3.10662

Keywords:

Adsorption, Coffee Grounds, COD, Fly Ash, Tofu wastewater

Abstract

The direct disposal of tofu industrial wastewater without treatment can have negative impacts on the environment due to its organic content. One effort that can be done is to process tofu liquid waste using the adsorption method. Nowadays, coffee shops are growing rapidly in indonesia, resulting in a lot of coffee grounds waste which can be used as raw material for activated charcoal because of its carbon content. In addition to coffee grounds, other waste in the form of fly ash is also used as an adsorbent because of its silica content. This study aims to determine the optimization of the composition of coffee grounds and fly ash adsorbents in the purification of tofu industry liquid waste and to determine the optimum contact time so that liquid waste is obtained in accordance with quality standards. Observation parameters include acidity (ph) and chemical oxygen demand (cod). Coffee grounds charcoal is activated using 0.1 n h₃po₄ solution then mixed with fly ash in a ratio of 20:80; 30:70; 50:50; 70:30; and 80:20. The adsorption process is carried out in batches for 60, 90, and 120 minutes. The results of the study showed the optimum composition of the adsorbent 20:80 and contact time 120 minutes with a final cod of 2,761 mg/l, ph 6.21, and a cod reduction of 80.46%.

References

[1] B. A. Jatyaraga, L. K. Atmadja, D. A. Anggorowati, and H. Setyawati, “Pengaruh Massa Magnesium Silikat (Magnesol) dan Waktu Operasi Pada Proses Pemurnian Biodiesel,” Konversi, vol. 4, no. 1, pp. 1–5, Apr. 2015.

[2] Barita Aritonang, Nova Florentina Ambarwati, Eka Margaretha Sinaga, and Ahmad Hafizullah Ritonga, “Sintesis dan Karakterisasi Arang Aktif Dari Kulit Salak Sebagai Adsorben Terhadap Kadar BOD, COD dan TSS Pada Limbah Cair Industri Tekstil,” Jurnal Multidisiplin Madani, vol. 2, no. 6, pp. 2611–2626, Jun. 2022, doi: 10.55927/mudima.v2i6.441.

[3] M. Septiani, Z. Darajat, D. Kurniawan, and I. Pasinda, “Kajian Perbandingan Efektivitas Adsorben Ampas Kopi Dan Fly Ash Pada Penurunan Konsentrasi Amonia (NH3) Dalam Limbah Cair Urea,” JST (Jurnal Sains Terapan), vol. 7, no. 2, pp. 52–59, Dec. 2021, doi: 10.32487/jst.v7i2.1171.

[4] D. Ifany, C. Nisa’, and A. Takwanto, “Pemanfaatan Bonggol Jagung Sebagai Adsorben Zat Warna Rhodamin B Menggunakan Metode Aktivasi Mechanochemical,” Distilat: Jurnal Teknologi Separasi, vol. 2022, no. 4, pp. 841–849, 2022, [Online]. Available: http://distilat.polinema.ac.id

[5] R. S. D. Lestari, D. K. Sari, A. Rosmadiana, and B. Dwipermata, “Pembuatan dan Karaktersasi Karbon Aktif Tempurung Kelapa dengan Aktivator Asam Fosfat Serta Aplikasinya Pada Pemurnian Minyak Goreng Bekas,” Jurnal TEKNIKA, vol. 12, no. 3, pp. 419–430, Oct. 2016.

[6] J. H. Nasution and iriany, “Pembuatan Adsorben Dari Cangkang Kerang Bulu 8ang Diaktivasi Secara Termal Sebagai Pengadsorpsi Fenol,” 2015.

[7] Z. Damanik et al., “Pengaruh Lama Aktifasi Dengan H3PO4 Dan Ukuran Butir Arang Cangkang Kelapa Sawit Terhadap Ukuran Pori dan Luas Permukaan Butir Arang Aktif,” Prosiding Seminar Nasional Lingkungan Lahan Basah, vol. 5, no. 1, p. 48, Apr. 2020.

[8] M. Cintia, N. Luh, G. R. Juliasih, D. Herasari, A. A. Kiswandono, and R. Supriyanto, “Studi Karbon Aktif Kayu Bakau (Rhizophora Mucronata) Sebagai Adsorben Pewarna Tekstil Biru Tua Kode 5 Menggunakan Spektrofotometer UV-VIS,” Analit: Analytical and Environmental Chemistry, vol. 7, no. 01, 2022, [Online]. Available: https://dx.doi.org/10.23960%2Faec.v7i1.2022.p54-67

[9] Z. Sartika, “The Effect of Active Carbon Sub-Bituminous Coal Activated Using HNO,” Jurnal Ilmiah Teknik Kimia UNPAM, vol. 3, no. 1, 2019.

[10] G. A. Arini and S. Aminah, “Pemanfaatan Serbuk Gergaji Kayu Jati (Tectona Grandis L.F) Sebagai Adsorben Logam CU (II),” Media Eksakta, vol. 16, no. 2, pp. 89–97, 2020.

Downloads

Published

2025-12-31

Citation Check

Most read articles by the same author(s)